Stars Tilda Swinton, Paul Dano, and Lily Collins walked the carpet, as did executive producer Brad Pitt.
The mansion is set on just over two acres of land in the gated and star-filled Laughlin Park neighborhood.
The French actress donned a black velvet gown embellished with crystals detailing.
Watch exclusive video of Brad Pitt and Marion Cotillard’s “Allied” movie costumes by Joanna Johnston.
“They’re the kind of people that you envy,” producer Steve Starkey said.
Brangelina may be over, but these red carpet looks will live on in memory.
Jolie will delve into the refugee crisis, World Refugee Day, and issues concerning survivors of sexual violence in conflict zones.
She will contribute to graduate lectures on women, peace and security.
Hoping to have the support of Marion Cotillard, Planeta Ginga Film Festival will be held in Rio’s favela to try to give children who live there hope.